1 Ocak 2013 Dergi makalesi Açık Erişim

Arici, Mursel; Bozoglu, Ceyda; Erdogmus, Ali; Ugur, Ahmet Lutfi; Koca, Atif

MARC21 XML

<?xml version='1.0' encoding='UTF-8'?>
<record xmlns="http://www.loc.gov/MARC21/slim">
  <leader>00000nam##2200000uu#4500</leader>
  <datafield tag="245" ind1=" " ind2=" ">
    <subfield code="a">Electrochemical and spectroelectrochemical properties of novel lutetium(III) mono- and bis-phthalocyanines</subfield>
  </datafield>
  <datafield tag="909" ind1="C" ind2="4">
    <subfield code="p">ELECTROCHIMICA ACTA</subfield>
    <subfield code="v">113</subfield>
    <subfield code="c">668-678</subfield>
  </datafield>
  <controlfield tag="001">16173</controlfield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="a">user-tubitak-destekli-proje-yayinlari</subfield>
  </datafield>
  <datafield tag="520" ind1=" " ind2=" ">
    <subfield code="a">Peripherally and non-peripherally substituted-mono and sandwich lutetium(III) phthalocyanines bearing 3,4-(dimethoxyphenylthio) substituents have been synthesized and characterized by elemental analysis, FT-IR, UV-vis spectroscopy and mass spectroscopy. Voltammetric, in-situ spectroelectrochemical, and in-situ electrocolorimetric characterization of the newly synthesized phthalocyanines were performed in solution. Changing the number and the position the substituents altered the reversibility of the electron transfer processes and affected the easy of electron transfer reactions. While the mono phthalocyanines had an oxidation reduction peak separation (Delta E-1/2) higher that 1.50V, this value decreased up to 0.36V due to the pi-pi interaction of phthalocyanine rings around the lutetium core. Solvent of the electrolytic system also affected the redox behaviors of the complexes considerably. In-situ electrocolorimetric method was applied to investigate the color of the electrogenerated anionic and cationic forms of the complexes for their possible electrochromic applications. (C) 2013 Elsevier Ltd. All rights reserved.</subfield>
  </datafield>
  <datafield tag="650" ind1="1" ind2="7">
    <subfield code="2">opendefinition.org</subfield>
    <subfield code="a">cc-by</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="u">Marmara Univ, Fac Engn, Dept Chem Engn, TR-34722 Istanbul, Turkey</subfield>
    <subfield code="a">Bozoglu, Ceyda</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="u">Yildiz Tekn Univ, Dept Chem, TR-34210 Istanbul, Turkey</subfield>
    <subfield code="a">Erdogmus, Ali</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="u">Canakkale 18 March Univ, Yenice Vocat Sch, Yenice Canakkale, Turkey</subfield>
    <subfield code="a">Ugur, Ahmet Lutfi</subfield>
  </datafield>
  <datafield tag="700" ind1=" " ind2=" ">
    <subfield code="u">Marmara Univ, Fac Engn, Dept Chem Engn, TR-34722 Istanbul, Turkey</subfield>
    <subfield code="a">Koca, Atif</subfield>
  </datafield>
  <datafield tag="980" ind1=" " ind2=" ">
    <subfield code="b">article</subfield>
    <subfield code="a">publication</subfield>
  </datafield>
  <datafield tag="542" ind1=" " ind2=" ">
    <subfield code="l">open</subfield>
  </datafield>
  <datafield tag="100" ind1=" " ind2=" ">
    <subfield code="u">Eskisehir Osmangazi Univ, Fac Arts &amp; Sci, Dept Chem, TR-26480 Eskisehir, Turkey</subfield>
    <subfield code="a">Arici, Mursel</subfield>
  </datafield>
  <datafield tag="260" ind1=" " ind2=" ">
    <subfield code="c">2013-01-01</subfield>
  </datafield>
  <controlfield tag="005">20210315093710.0</controlfield>
  <datafield tag="909" ind1="C" ind2="O">
    <subfield code="o">oai:zenodo.org:16173</subfield>
    <subfield code="p">user-tubitak-destekli-proje-yayinlari</subfield>
  </datafield>
  <datafield tag="856" ind1="4" ind2=" ">
    <subfield code="z">md5:8f46d82a3d8f138429073a469ece3bc2</subfield>
    <subfield code="s">214</subfield>
    <subfield code="u">https://aperta.ulakbim.gov.trrecord/16173/files/bib-a1216f2f-52e3-47a3-8f17-454a79c8d5fe.txt</subfield>
  </datafield>
  <datafield tag="540" ind1=" " ind2=" ">
    <subfield code="u">http://www.opendefinition.org/licenses/cc-by</subfield>
    <subfield code="a">Creative Commons Attribution</subfield>
  </datafield>
  <datafield tag="024" ind1=" " ind2=" ">
    <subfield code="a">10.1016/j.electacta.2013.09.088</subfield>
    <subfield code="2">doi</subfield>
  </datafield>
</record>