1 Ocak 2013 Dergi makalesi Açık Erişim

Tar, Haja; Esen, Duygu Sevinc; Aydin, Meral; Ley, Christian; Arsu, Nergis; Allonas, Xavier

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        "affiliation": "Univ Haute Alsace, Lab Macromol Photochem & Engn, F-68093 Mulhouse, France", 
        "name": "Tar, Haja"
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      {
        "affiliation": "Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey", 
        "name": "Esen, Duygu Sevinc"
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      {
        "affiliation": "Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey", 
        "name": "Aydin, Meral"
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      {
        "affiliation": "Univ Haute Alsace, Lab Macromol Photochem & Engn, F-68093 Mulhouse, France", 
        "name": "Ley, Christian"
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      {
        "affiliation": "Yildiz Tech Univ, Dept Chem, TR-34220 Istanbul, Turkey", 
        "name": "Arsu, Nergis"
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      {
        "affiliation": "Univ Haute Alsace, Lab Macromol Photochem & Engn, F-68093 Mulhouse, France", 
        "name": "Allonas, Xavier"
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    "description": "A new photoinitiator for free radical photopolymerization, belonging to the thioxanthone derivatives, was synthesized and characterized It was found that the compound absorbs over the whole UV-vis spectrum with relatively high absorption coefficients. Fluorescence studies reveal that three different singlet excited states are responsible for this absorption. Phosphorescence and laser flash photolysis evidence the formation of a triplet state from which a photoreduction can occur. Consequently, initiating radicals were formed which are able to initiate the photopolymerization of methyl methacrylate in DMF. Finally, the photopolymerization of acrylates was performed in film at different wavelengths such as 392, 476, 532, and 632 nm, emphasizing the possibility to use this novel photoinitiator when panchromatic irradiation is required.", 
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      "issue": "9", 
      "pages": "3266-3272", 
      "title": "MACROMOLECULES", 
      "volume": "46"
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    "title": "Panchromatic Type II Photoinitiator for Free Radical Polymerization Based on Thioxanthone Derivative"
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