1 Ocak 2013 Dergi makalesi Açık Erişim

Awheda, Ismail; Saygili, Nezire; Garner, A. Christopher; Wallis, John D.

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        "affiliation": "Nottingham Trent Univ, Sch Sci & Technol, Nottingham NG11 8NS, England", 
        "name": "Awheda, Ismail"
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      {
        "affiliation": "Hacettepe Univ, Fac Pharm, Dept Basic Pharmaceut Sci, TR-06100 Ankara, Turkey", 
        "name": "Saygili, Nezire"
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      {
        "affiliation": "Nottingham Trent Univ, Sch Sci & Technol, Nottingham NG11 8NS, England", 
        "name": "Garner, A. Christopher"
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      {
        "affiliation": "Nottingham Trent Univ, Sch Sci & Technol, Nottingham NG11 8NS, England", 
        "name": "Wallis, John D."
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    "description": "The cyclic thionocarbamate of alaninol undergoes nucleophilic attack by sulfur nucleophiles at 5-C to give 1-thiopropyl-2-amine derivatives when derivatised on nitrogen with a Boc group. Iodide under microwave conditions causes a rearrangement to the isomeric thiazolidinone, while \"hard\" nucleophiles react at the thione group to yield a variety of product types by subsequent C-N or C-O cleavage. X-ray crystallography studies showed that the N-Boc group reduces delocalisation of electron density from nitrogen into the thione group, and thus promotes activation of the ring to nucleophilic attack.", 
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      "issue": "47", 
      "pages": "24997-25009", 
      "title": "RSC ADVANCES", 
      "volume": "3"
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    "title": "Activation and regioselectivity of five-membered cyclic thionocarbamates to nucleophilic attack"
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