1 Ocak 2013 Dergi makalesi Açık Erişim

Akar, Kiymet Berkil; Cakmak, Osman

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        "affiliation": "Gaziosmanpasa Univ, Dept Bioengn, Fac Engn & Nat Sci, TR-60250 Tokat, Turkey", 
        "name": "Akar, Kiymet Berkil"
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        "affiliation": "Gaziosmanpasa Univ, Dept Chem, Fac Arts & Sci, TR-60250 Tokat, Turkey", 
        "name": "Cakmak, Osman"
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    "description": "Selective and efficient methods for the preparation of both 2,7,9,10-tetrabromoanthracene 11 and 2,6,9,10-tetrabromoanthracene 12 are described. Photobromination of 2,9,10-tribromoanthracene 8 resulted in the formation of only one stereoisomeric heptabromide 10. Whilst thermal aromatization of the trans,cis,trans-1,2,3,4,6,9,10-heptabromo-1,2,3,4-tetrahydroanthracene 10 gave mainly 2,6,9, 10-tetrabromoanthracene 12, the pyridine-induced elimination yielded 2,7,9,10-tetrabromoanthracene 11 as the only final product. Tetrabromide 11 was transformed into 2,7,9,10-tetracyanoanthracene 14, by copper-assisted nucleophilic substitution reaction, as a potential photoconductive product. (C) 2012 Elsevier Ltd. All rights reserved.", 
    "doi": "10.1016/j.tetlet.2012.11.048", 
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      "issue": "4", 
      "pages": "312-314", 
      "title": "TETRAHEDRON LETTERS", 
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    "title": "Polybrominated anthracenes: selective synthesis of tetrabromoanthracenes as precursors for the corresponding tetracyanoanthracenes"
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