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Photocatalytic hydrogen evolution via solar-driven Water splitting by CuSbS2 with different shapes

Sarilmaz, Adem; Genc, Eminegul; Aslan, Emre; Ozen, Abdurrahman; Yanalak, Gizem; Ozel, Faruk; Patir, Imren Hatay


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        "affiliation": "Karamanoglu Mehmetbey Univ, Dept Met & Mat Engn, TR-70200 Karaman, Turkey", 
        "name": "Sarilmaz, Adem"
      }, 
      {
        "affiliation": "Selcuk Univ, Dept Nanotechnol & Adv Mat, TR-42250 Konya, Turkey", 
        "name": "Genc, Eminegul"
      }, 
      {
        "affiliation": "Selcuk Univ, Dept Biochem, TR-42250 Konya, Turkey", 
        "name": "Aslan, Emre"
      }, 
      {
        "affiliation": "Karamanoglu Mehmetbey Univ, Dept Met & Mat Engn, TR-70200 Karaman, Turkey", 
        "name": "Ozen, Abdurrahman"
      }, 
      {
        "affiliation": "Selcuk Univ, Dept Biochem, TR-42250 Konya, Turkey", 
        "name": "Yanalak, Gizem"
      }, 
      {
        "name": "Ozel, Faruk"
      }, 
      {
        "affiliation": "Selcuk Univ, Dept Biotechnol, TR-42250 Konya, Turkey", 
        "name": "Patir, Imren Hatay"
      }
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    "description": "Chalcostibite (CuSbS2) semiconductor catalyst has been intensively preferred towards energy conversion processes because of its suitable bandgap, high absorption coefficient and photocatalytic activity. Herein, the photocatalytic hydrogen evolution reaction (HER) was carried out by using different shapes (Rod (R) and Dot (D)) of copper-antimony sulfides. The hydrogen evolution activities of R-CuSbS2 and D-CuSbS2 were investigated under the visible light irradiation by using eosin-Y (EY) dye and triethanolamine (TEOA) as photosensitizer and an electron donor, respectively. The photocatalytic HER rates of R-CuSbS2 and D-CuSbS2 were determined as 2140 innolg(-1) h(-1) and 825 mu molg(-1) h(-1), respectively. R-CuSbS2 displayed higher photocatalytic activity in comparison with D-CuSbS2. The results of photocatalytic activity belonging to chalcostibite catalysts could be explained by efficient charge separation efficiency of 1D microrod materials.", 
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      "title": "JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY", 
      "volume": "400"
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    "publication_date": "2020-01-01", 
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    "title": "Photocatalytic hydrogen evolution via solar-driven Water splitting by CuSbS2 with different shapes"
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