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UNSYMMETRICAL PHTHALOCYANINES WITH A SINGLE MACROCYCLIC SUBSTITUENT

1992    MUSLUOGLU, E; GUREK, A; AHSEN, V; GUL, A; BEKAROGLU, O

Unsymmetrical phthalocanines (5 - 7) with a single macrocyclic substituent are synthesized by the reaction of the boron complex of phthalonitrile (1) with the iminoisoindoline derivatives 2 - 4 of macrocyclic compounds, i.e. 15-crown-5, mono-aza-15-crown-5, and tetraazacyclotetradecane. The mono-macrocycle-substituted phthalocyanines are less soluble than the tetra-substituted one.