1 Ocak 1997 Dergi makalesi Açık Erişim

Icli, S; Icil, H; Whitten, DG; Sayil, C; Dityapak, I

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{
  "@context": "https://schema.org/", 
  "@id": 103791, 
  "@type": "ScholarlyArticle", 
  "creator": [
    {
      "@type": "Person", 
      "name": "Icli, S"
    }, 
    {
      "@type": "Person", 
      "name": "Icil, H"
    }, 
    {
      "@type": "Person", 
      "name": "Whitten, DG"
    }, 
    {
      "@type": "Person", 
      "name": "Sayil, C"
    }, 
    {
      "@type": "Person", 
      "name": "Dityapak, I"
    }
  ], 
  "datePublished": "1997-01-01", 
  "description": "Singlet energies and fluorescence quantum yields of synthesized dihydrocarbazolocarbazole, 1, dimethylcarbazolocarbazole, 2, dibenzylcarbazolocarbazole, 3, were measured to be between 76.5-74.3 kcal/mol and 0.07-0.02 respectively. A Stern-Volmer plot of fluorescence quenching of dihydrocarbazolocarbazole, 1, with 2,4,5,7-tetranitrofluorenone, 4, has given a rate constant of quenching of k(q) = 7.4 x 10(12) M(-1)s(-1). The free energies of the exothermic electron transfer reaction are calculated to be -33.6 kcal/mol for dihydrocarbazolocarbazole, 1, and -26.8 kcal/mol for dimethylcarbazolocarbazole, 2. High values for the rate of fluorescence quenching and the free energies are the evidence for an electron transfer process between these strong pi-electron donor-acceptor complexed molecules.", 
  "headline": "Fluorescence quenching between strong pi-electron donor-acceptors of carbazolocarbazole and tetranitrofluorenone leading to electron transfer", 
  "identifier": 103791, 
  "image": "https://aperta.ulakbim.gov.tr/static/img/logo/aperta_logo_with_icon.svg", 
  "license": "http://www.opendefinition.org/licenses/cc-by", 
  "name": "Fluorescence quenching between strong pi-electron donor-acceptors of carbazolocarbazole and tetranitrofluorenone leading to electron transfer", 
  "url": "https://aperta.ulakbim.gov.tr/record/103791"
}