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NMR ASSIGNMENTS AND ABSOLUTE STEREOCHEMISTRY OF 2 GUAIANOLIDE SESQUITERPENES FROM TANACETUM-DENSUM SUBSP AMANI

ULUBELEN, A; GOREN, N; JIANG, TY; SCOTT, L; TIANASOARAMOMOJY, M; SNYDER, JK


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{
  "URL": "https://aperta.ulakbim.gov.tr/record/102601", 
  "abstract": "The guaianolide sesquiterpene pyrethroidinin (1) and the corresponding ketone parishin A (2) were isolated from Tanacetum densum subsp, amani (Asteraceae). The absolute stereochemistry of 1 was established as (1R, 3R, 6S, 7S, 10R) on the basis of the differential shielding in the H-1 NMR spectra of the (-)- and (+)-O-methylmandelate esters. The structure, including absolute stereochemistry, of 2 was confirmed by oxidation of 1 with Jones' reagent.", 
  "author": [
    {
      "family": "ULUBELEN", 
      "given": " A"
    }, 
    {
      "family": "GOREN", 
      "given": " N"
    }, 
    {
      "family": "JIANG", 
      "given": " TY"
    }, 
    {
      "family": "SCOTT", 
      "given": " L"
    }, 
    {
      "family": "TIANASOARAMOMOJY", 
      "given": " M"
    }, 
    {
      "family": "SNYDER", 
      "given": " JK"
    }
  ], 
  "container_title": "MAGNETIC RESONANCE IN CHEMISTRY", 
  "id": "102601", 
  "issue": "11", 
  "issued": {
    "date-parts": [
      [
        1995, 
        1, 
        1
      ]
    ]
  }, 
  "page": "900-904", 
  "title": "NMR ASSIGNMENTS AND ABSOLUTE STEREOCHEMISTRY OF 2 GUAIANOLIDE SESQUITERPENES FROM TANACETUM-DENSUM SUBSP AMANI", 
  "type": "article-journal", 
  "volume": "33"
}
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