Published January 1, 2000 | Version v1
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Gel growth in free radical crosslinking copolymerization: Effect of inactive gel radicals

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A kinetic model is presented for the post-gelation period of free-radical crosslinking copolymerization. The model takes into account the trapped radical centers in the gel forming system. It was shown that the weight fraction of sol, W-s2 relates to the number of crosslinked units per weight-average primary molecule. epsilon, through the equation

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