Published January 1, 2018 | Version v1
Journal article Open

The investigation of sky-blue emitting anthracene-carbazole derivatives: Synthesis, photophysics and OLED applications

  • 1. TUBITAK Marmara Res Ctr, Inst Chem Technol, Pb 21, TR-41470 Gebze, Kocaeli, Turkey
  • 2. Erzurum Tech Univ, Dept Fundemantal Sci, Erzurum, Turkey
  • 3. Sungkyunkwan Univ, Sch Chem Engn, 2066 Seobu Ro, Suwon 440746, Gyeonggi Do, South Korea
  • 4. Van Yuzuncu Yil Univ, Dept Chem, Van, Turkey
  • 5. Istanbul Tech Univ, Dept Chem, TR-34469 Istanbul, Turkey

Description

New well-defined structurally different 9,10-bis(9-hexyl-6-((E)-styryl)-9H-carbazol-3-yl)anthracene derivatives, shortly named "6a, 6b and 6c", with side groups having electron donating and withdrawing were systematically synthesized using Suzuki cross-coupling and Vilsmeier-Haack reactions. The impact of electron donating and withdrawing groups and their influence on the molecules photophysical properties has been investigated. The materials showed sky-blue emissions with high internal quantum efficiencies. Based on photophysical investigations the most promising molecule (6a) has been selected and high efficiency OLEDs with external quantum efficiency at very low current efficiency (similar to 1 mA/cm(2)) reaching 5% (doped) were obtained.

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