Published January 1, 2010 | Version v1
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Synthesis, structure and metal ion binding of di-(1,8-naphtho)-16-crown-4 compounds

  • 1. MIT, Dept Chem, Xray Diffract Facil, Cambridge, MA 02139 USA
  • 2. Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA

Description

The syntheses of two di(1,8-naphtho)-16-crown-4 compounds are described. In the X-ray structure of di(1,8-naphtho)-16-crown-4, the compound crystallizes in the orthorhombic space group Pna2(1) with four molecules per asymmetric unit. Alkali metal cation selectivities of the ionophores are assessed in solvent polymeric membrane electrodes.

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