Published January 1, 2013 | Version v1
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Customized vic-dioximes and their metal complexes for enhanced chemical sensing of polar organic molecules

  • 1. TUBITAK Marmara Res Ctr, Mat Inst, TR-41470 Gebze, Kocaeli, Turkey

Description

Vic-dioximes and their nickel and palladium complexes were customized with fluorinated substituents including moieties capable of hydrogen bonding to improve selectivity in chemical sensing of polar analytes. Many analytes of interest in applications as diverse as food stuff or air quality analysis are of polar chemical nature. Such compounds, e.g., ketones, esters or alcohols contribute to the aroma of fruits and food products, but are also in industrial use as solvents in paints or in the production of plastic products. The gas sensing properties of the new compounds are demonstrated using the quartz crystal microbalance and selected volatile organic compounds as analytes.

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