Yayınlanmış 1 Ocak 2019
| Sürüm v1
Dergi makalesi
Açık
Total Synthesis of Olivacine and Ellipticine via a Lactone Ring Opening and Aromatization Cascade
Oluşturanlar
- 1. TUBITAK Marmara Res Ctr, Inst Chem Technol, TR-41470 Kocaeli, Turkey
- 2. Suleyman Demirel Univ, Dept Chem, TR-32260 Isparta, Turkey
Açıklama
Effective preparation of olivacine and ellipticine via late-stage D-ring cyclization is described. Key features of the synthetic routes include trifluoroacetic acid-mediated formation of a lactone that is fused to a tetrahydrocarbazole derivative and its one-pot two-step ring opening and aromatization mediated by para-toluenesulfonic acid and palladium on carbon, respectively.
Dosyalar
bib-22b23e85-703b-4f63-aa78-6f4097a887f9.txt
Dosyalar
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