Yayınlanmış 1 Ocak 2009
| Sürüm v1
Dergi makalesi
Açık
Preparation of iron phthalocyanine complex bearing four tetraazamacrocycles as a precursor for oxidation catalyst with two catalytic sites
Oluşturanlar
- 1. Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey
- 2. Univ Lyon 1, CNRS, IRCELYON, UMR 5256, F-69626 Villeurbanne, France
Açıklama
The synthesis of the iron phthalocyanine bearing four fused tetraaza macrocycles starting from N,N',N '',N'''-tetrakis(p-tolylsulfonyl)triethylenetetraamine and 1,2-dibromo-4,5-bis-(bromomethyl) benzene is reported. The exchange of protecting tosyl groups by acetyl groups was necessary to obtain iron phthalocyanine. The efficiency of iron phthalocyanine as oxidation catalyst was tested for the practically important oxidation of 2,3,6-trimethylphenol (TMP) at different reaction conditions.
Dosyalar
bib-5785796d-a3e9-4e23-b7a2-7266b8164148.txt
Dosyalar
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