Published January 1, 2011 | Version v1
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Synthesis, characterization, and application to transfer hydrogenation of eta(6)-(3,4,5-trimethoxybenzyl)-eta(1)-N-heterocyclic carbene-ruthenium complex

  • 1. Inonu Univ, Dept Chem, Fac Sci & Art, TR-44280 Malatya, Turkey
  • 2. Ege Univ, Dept Chem, Fac Sci, TR-35100 Bornova, Turkey
  • 3. Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey
  • 4. Sci & Technol Res Council Turkey, Basic Sci Res Grp, TR-06100 Ankara, Turkey

Description

A new chelating ruthenium complex was synthesized using an electron-rich olefin and [RuCl2(p-cymene)](2) and characterized structurally and spectroscopically. The structure of the complex was verified using X-ray crystallography. The complex displayed high activities in transfer hydrogenation.

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