Polarons in boron doped iron phosphate glasses

The electrical conductivity and dielectric properties of xB(2)O(3)-(40-x)Fe2O3-60P(2)O(5) (x = 6-20, mol%) glasses were investigated in the frequency range from 0.01 Hz to 1 MHz and the temperature range from 303 K to 523 K. At temperatures below 523 K an ac conductivity and the dielectric constant follow the universal dielectric response (UDR), being typical for hopping or tunneling of localized charge carriers. A detailed analysis of the temperature dependence of the UDR parameter s in terms of the theoretical model for tunneling of small polarons revealed that below 523 K this mechanism governs the charge transport in these glasses. The comparison of the values of characteristic coefficients W-infinity and alpha determined by two different methods confirms the polaronic behavior of boron doped iron phosphate glasses. (c) 2012 Elsevier B.V. All rights reserved.