Yayınlanmış 1 Ocak 2012
| Sürüm v1
Dergi makalesi
Açık
Synthesis and biological evaluation of optically active conjugated gamma- and delta-lactone derivatives
- 1. Middle E Tech Univ, Dept Chem, TR-06800 Ankara, Turkey
Açıklama
An efficient synthesis of racemic and both enantiomeric forms of heteroaryl substituted gamma- and delta-lactone derivatives derived from allyl and homoallyl alcohol backbones has been accomplished via ring closing metathesis reaction. 2-Heteroaryl substituted allyl and homoallyl alcohols have been efficiently resolved through enzymatic method with high ee (97-99%) and known stereochemistry. Antimicrobial and antioxidant activities of target lactones were evaluated. (C) 2012 Elsevier Ltd. All rights reserved.
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