Published January 1, 2012
| Version v1
Journal article
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Bromination of Benz[f]indene: Synthesis of New Benz[f]indane Derivatives
Creators
- 1. Sakarya Univ, Fac Art & Sci, Dept Chem, TR-54187 Adapazari, Turkey
- 2. Gaziosmanpasa Univ, Fac Art & Sci, Dept Chem, TR-60240 Tokat, Turkey
Description
The bromination reactions of benz[f]indene 1 were investigated with molecular bromine and photobromination. Dibromo- and tribromobenz[f]indane were synthesised by bromination of benz[f] indene 1. Subsequent reactions of dibromobenz[f]indane 2 were accomplished with various silver salts (silver acetate, perchlorate, sulphate and nitrate). Treatment of trans-1-acetate-2-bromobenz[f]indane 6 with sodium methoxide resulted in the formation of corresponding 1,2-oxide-benz[f]indane 10.
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