Novel polymeric potassium complex: Its synthesis, structural characterization, photoluminescence and electrochemical properties

In this paper, we obtained a novel poly(vanillinato potassium) complex (PVP) as a single crystal and characterized by analytical and spectroscopic methods. A single crystal of the PVP was obtained from the acetone solution. X-ray structural data show that crystals contain polymeric K+ complex of vanillin. Each potassium ion in the polymeric structure is identical and seven-coordinate, bonded to two methoxy, two phenoxy and three aldehyde oxygen atoms from four vaniline molecules. Two aldehyde oxygen atoms are bridging between potassium ions. It crystallizes in the monoclinic system, space group P2(1)/c, with lattice parameters a = 9.6215(10) (A) over dot, b = 17.4139(19) (A) over dot, c = 9.6119(10) (A) over dot, beta = 100.457(2)degrees and Z = 4. Thermal properties of the PVP were investigated by TGA, DTA and DSC methods. The electrochemical properties of the complex were studied in different solvents and at various scan rates. The luminescence properties of the complex in different solvents and at different pH values have been investigated. The results show that the complex exhibits more efficient luminescence property in CH3CN and n-butanol. (C) 2011 Elsevier B.V. All rights reserved.