Yayınlanmış 1 Ocak 2012 | Sürüm v1
Dergi makalesi Açık

Preparation of a series of Ru(II) complexes with N-heterocyclic carbene ligands for the catalytic transfer hydrogenation of aromatic ketones

  • 1. Inonu Univ, Fac Sci, Dept Chem, TR-44280 Malatya, Turkey
  • 2. Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey
  • 3. Ondokuz Mayis Univ, Dept Phys, TR-55139 Kurupelit, Turkey

Açıklama

The reaction of [RuCl2(p-cymene](2) with Ag-N-heterocyclic carbene (NHC) complexes yields a series of [(p-cymene) Ru(NHC)] complexes (2a-f). All synthesised compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structure of 2a was determined by X-ray crystallography. All complexes have been tested as catalysts for the transfer hydrogenation of aromatic ketones, showing excellent activity in this reaction.

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