Published January 1, 2012
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Preparation of a series of Ru(II) complexes with N-heterocyclic carbene ligands for the catalytic transfer hydrogenation of aromatic ketones
Creators
- 1. Inonu Univ, Fac Sci, Dept Chem, TR-44280 Malatya, Turkey
- 2. Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey
- 3. Ondokuz Mayis Univ, Dept Phys, TR-55139 Kurupelit, Turkey
Description
The reaction of [RuCl2(p-cymene](2) with Ag-N-heterocyclic carbene (NHC) complexes yields a series of [(p-cymene) Ru(NHC)] complexes (2a-f). All synthesised compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structure of 2a was determined by X-ray crystallography. All complexes have been tested as catalysts for the transfer hydrogenation of aromatic ketones, showing excellent activity in this reaction.
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