Yayınlanmış 1 Ocak 2012 | Sürüm v1
Dergi makalesi Açık

Butylbis(dimethylglyoximato-kappa N-2,N ')(pyridine-kappa N)cobalt(III)

  • 1. Univ Buenos Aires, DQIAQF INQUIMAE, Buenos Aires, DF, Argentina
  • 2. Purbanchal Univ, Fac Sci & Technol, Biratnagar, Nepal

Açıklama

In the title compound, [Co(C4H9)(C4H7N2O2)(2)(C5H5N)], which was prepared as a model complex of vitamin B-12, the Co-III atom is coordinated by a butyl group, a pyridine and two N,N'-bidentate dimethylglyoximate ligands in a distorted octahedral geometry. The bis-chelating dimethylglyoximate ligands, which occupy equatorial sites, are linked by strong intramolecular O-H center dot center dot center dot O hydrogen bonds.

Dosyalar

bib-be5a3012-1ef2-413b-b2b6-7153d5ba815e.txt

Dosyalar (182 Bytes)

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md5:1a1afc714b6f0969f6d59afc6e864d8e
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