The structural, magnetic, and magnetocaloric properties of In-doped Mn2-xCrxSb

Mn2-xCrxSb exhibits an antiferromagnetic-ferrimagnetic transition of which the temperature can be changed by controlling the Cr concentration. Increasing the Cr content from x = 0.05 to 0.13 raises the transition temperature from about 180 K up to around room temperature. To suppress the inevitable ferromagnetic MnSb impurity phase, we partially replace Sb by In. Mn2-xCrxSb1-yIny alloys have an antiferromagnetic-ferrimagnetic transition and a narrow transition hysteresis and exhibit the inverse magnetocaloric effect. We examine the magnetocaloric effect from the magnetization and direct adiabatic temperature-change measurements. (C) 2015 AIP Publishing LLC.