Published January 1, 2015 | Version v1
Journal article Open

High Capacity and High Density Functional Conductive Polymer and SiO Anode for High-Energy Lithium-Ion Batteries

  • 1. Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA
  • 2. Istanbul Tech Univ, Energy Inst, TR-34469 Istanbul, Turkey
  • 3. Inst Rech Elect Hydroquebec IREQ, Montreal, PQ H2Z 1A4, Canada

Description

High capacity and high density functional conductive polymer binder/SiO electrodes are fabricated and calendered to various porosities. The effect of calendering is investigated in the reduction of thickness and porosity, as well as the increase of density. SiO particle size remains unchanged after calendering. When compressed to an appropriate density, an improved cycling performance and increased energy density are shown compared to the uncalendered electrode and overcalendered electrode. The calendered electrode has a high-density of similar to 1.2 g/cm(3). A high loading electrode with an areal capacity of similar to 3.5 mAh/cm(2) at a C/10 rate is achieved using functional conductive polymer binder and simple and effective calendering method.

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