Published January 1, 2015
| Version v1
Journal article
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Synthesis of Cu(II)-Organophosphonate Framework with Predefined Void Spaces
Creators
- 1. Gebze Tech Univ, Dept Chem, TR-41400 Kocaeli, Turkey
- 2. Yildiz Tech Univ, Dept Chem, TR-34010 Istanbul, Turkey
- 3. Yildiz Tech Univ, Dept Bioengineering, Fac Chem & Met Engn, TR-34210 Istanbul, Turkey
- 4. ETH, CH-8093 Zurich, Switzerland
- 5. Univ Bremen, Inst Anorgan Chem, D-28359 Bremen, Germany
Description
Here we report the first utilization of the novel methane tetra-p-phenylphosphonic acid (MTPPA) ligand for the preparation of metal complexes with Cu(II). The hydrothermal and solvothermal reactions of tetratopic MTPPA as a bridging ligand in conjunction with the square pyramidal {Cu(terpy)}(2+) and {Cu-2(pbterpy)}(4+), (where terpy = 2,2':6',2 ''-Terpyridine and pbterpy = 4',4 ''''-(1,4-Phenylene)-bis(2,2':6',2 ''-terpyridine)) as prefixed corner building units have produced one-dimensional [{Cu(terpy)}(2)(MTPPA-H-5) (MTPPA-H-6)]center dot(4.2H(2)O)(H3O) (1) and two-dimensional [{Cu-2(pbterpy)}MTPPA-H-4] (2), respectively. The structures were characterized by single crystal X-ray diffraction and TGA.
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