Yayınlanmış 1 Ocak 2019
| Sürüm v1
Dergi makalesi
Açık
Alkali Phosphonate Metal-Organic Frameworks
Oluşturanlar
- 1. Tech Univ Berlin, Lebensmittelchem & Toxikol, Gustav Meyer Allee 25, D-13355 Berlin, Germany
- 2. Gebze Tech Univ, Dept Chem, TR-41400 Kocaeli, Turkey
- 3. UCL, Dept Chem Engn, London WC1E 7JE, England
- 4. Univ Bremen, Inst Anorgan Chem & Kristallog, Leobener Str, D-28359 Bremen, Germany
Açıklama
A new family of porous metal-organic frameworks (MOFs), namely alkali phosphonate MOFs, is reported. [Na2Cu(H(4)TPPA)].(NH2(CH3)(2))(2) (GTUB-1) was synthesized using the tetratopic 5,10,15,20-tetrakis[p-phenylphosphonic acid] porphyrin (H-8-TPPA) linker with planar X-shaped geometrical core. GTUB-1 is composed of rectangular void channels with BET surface area of 697 m(2) g(-1). GTUB-1 exhibits exceptional thermal stability. The toxicity analysis of the (H-8-TPPA) linker indicates that it is well tolerated by an intestinal cell line, suggesting its suitability for creating phosphonate MOFs for biological applications.
Dosyalar
bib-ca32f912-564d-406b-9335-b526ca728afe.txt
Dosyalar
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