Yayınlanmış 1 Ocak 2020 | Sürüm v1
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Blue-Light Photocleavable Protecting Groups Based on Benzothiadiazole Scaffolds

  • 1. Iowa State Univ, Dept Chem, Ames, IA 50011 USA

Açıklama

An unexpected nucleophilic aromatic substitution lead to a novel benzothiadiazole scaffold that bore the functional group pattern associated with benzyl-type photocleavable protecting groups. The new molecules display efficient photochemical release of leaving groups with blue light. The performance of both ortho- and meta-substituted derivatives was probed through both structural manipulation and computational metrics to improve performance.

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bib-e27c7581-4711-4710-b0b3-417c3f3c27d5.txt

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md5:e894b33034357f8b71f8bdbc53f00b9f
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