Published January 1, 2014
| Version v1
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Intramolecular excimer formation in hexakis(pyrenyloxy)cyclotriphosphazene: photophysical properties, crystal structure, and theoretical investigation
Creators
- 1. Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey
- 2. Canakkale Onsekiz Mart Univ, Biga Vocat Sch, Dept Chem Technol, TR-17200 Biga, Canakkale, Turkey
Description
A hexakis(pyrenyloxy) cyclotriphosphazene is synthesized by the reaction of N3P3Cl6 with 2-hydroxypyrene, and its excimer emission through intramolecular interactions in solution and in the solid state has been investigated by fluorescence spectroscopy and X-ray crystallography. Thermal and electrochemical properties were investigated. A DFT benchmark study has been performed to evaluate the intramolecular interactions and molecular orbital levels by comparing with the experimental results.
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