Published January 1, 2014 | Version v1
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A new reagent for the synthesis of [26]hexaphyrin: N-sulfonyl aldimine

  • 1. Hacettepe Univ, Dept Chem, TR-06800 Ankara, Turkey

Description

The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions. (C) 2013 Elsevier Ltd. All rights reserved.

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