Yayınlanmış 1 Ocak 2014 | Sürüm v1
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Atropisomeric Dyes: Axial Chirality in Orthogonal BODIPY Oligomers

  • 1. Bilkent Univ, UNAM Natl Nanotechnol Res Ctr, TR-06800 Ankara, Turkey
  • 2. Bilkent Univ, Dept Chem, TR-06800 Ankara, Turkey

Açıklama

A dissymmetrically substituted orthogonal BODIPY dimer and an orthogonal BODIPY trimer exist as two stable conformers, which are in fact atropisomeric enantiomers. The racemic mixture can be separated by HPLC using a chiral stationary phase. These enantiomeric derivatives hold great potential as chiral agents in asymmetric synthesis, fluorogenic/chromogenic sensing, and biological applications.

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