Published January 1, 2016
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Asymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C-2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes
- 1. Siirt Univ, Sci & Technol Applicat & Res Ctr SUBTAM, TR-56000 Siirt, Turkey
- 2. Dicle Univ, Fac Sci, Dept Chem, TR-21280 Diyarbakir, Turkey
Description
Known Ru(II), Rh(I) and Ir(III) complexes of C-2-symmetric ferrocenyl based chiral bis(phoshinite) ligands were catalyzed the asymmetric transfer hydrogenation of alkyl/aryl or alkyl methyl ketones. Corresponding secondary alcohols were obtained with high enantioselectivities up to 98% ee and reactivities using iso-propanol as the hydrogen source. (C) 2016 Elsevier B.V. All rights reserved.
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