Published January 1, 2016
| Version v1
Journal article
Open
Synthesis of aminomethyl quinazoline based ruthenium (II) complex and its application in asymmetric transfer hydrogenation under mild conditions
Creators
- 1. Kahramanmaras Sutcu Imam Univ, Dept Chem, Fac Sci & Letters, TR-46100 Kahramanmaras, Turkey
- 2. Osmaniye Korkut Ata Univ, Fac Sci & Letters, Dept Chem, TR-80000 Osmaniye, Turkey
Description
The new chiral aminomethyl quinazoline (amq) type ligand derived from L-phenylalanine was synthesized and coordinated with [RuCl2(PPh3) dppb] to obtain ruthenium(II) complex. This catalyst displayed considerable reactivity (up to 97% ee and 99% conversion) in the asymmetric transfer hydrogenation of ketones using 2-propanol as a hydrogen source in the presence of NaOiPr. (C) 2016 Elsevier B.V. All rights reserved.
Files
bib-d55165c9-3a3f-408b-861b-282ceed22e9f.txt
Files
(283 Bytes)
| Name | Size | Download all |
|---|---|---|
|
md5:05a433a86da4616c1f89288c9b0f3fc9
|
283 Bytes | Preview Download |