Yayınlanmış 1 Ocak 2016 | Sürüm v1
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Isoquinoline-substituted hybrid compounds: Synthesis and computational studies

  • 1. Yuzuncu Yil Univ, Dept Chem, TR-65080 Van, Turkey

Açıklama

The one-pot synthesis of novel 1,4-disubstituted 1,2,3-triazoles from isoquinoline-substituted homopropargyl alcohol backbone is described (42-88% yields). A ring closing metathesis (RCM) reaction and an intramolecular Pauson-Khand reaction (PKR) of enyne system derived from a homopropargyl alcohol backbone to afford the corresponding isoquinoline-substituted dihydropyran and cyclopentenone-pyran, respectively, are also described (54% and 78% yields). Information about the structural, electronic and physico-chemical properties of the novel compounds, obtained by density functional theory application, is also reported.

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