Published January 1, 2016
| Version v1
Journal article
Open
Bicyclic N-heterocyclic carbene (NHC) ligand precursors and their palladium complexes
- 1. Adnan Menderes Univ, Fac Arts & Sci, Dept Chem, Aydin, Turkey
- 2. Ondokuz Mayis Univ, Dept Secondary Sch Sci & Math Educ, Fac Educ, Samsun, Turkey
- 3. Ege Univ, Dept Chem, Fac Sci, Izmir, Turkey
Description
Eight bicyclic amidinium precursors (3), prepared from R,S-tmcp (R,S-tmcp: (1R,3S)-diamino-1,2,2-trimethylcyclopentane) were described. Only five of the precursors (3a-e) could be converted to palladium complexes, (PdX2(6,7-NHC)PEPPSI) (4) by treatment with PdCl2, K2CO3, and pyridine (additional KBr was used for (PdBr2(6,7-NHC)PEPPSI)). The salts and complexes were fully characterized by spectroscopic methods and X-ray crystallography.
Files
bib-ac0ae6cb-bcf0-4fc6-a32e-6e00a62aaf58.txt
Files
(203 Bytes)
| Name | Size | Download all |
|---|---|---|
|
md5:b403cb36cf3dcb4037c046147ceefa2c
|
203 Bytes | Preview Download |