Published January 1, 2017
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From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification
Creators
- 1. Abdullah Gul Univ, Dept Mat Sci & Nanotechnol Engn, TR-38080 Kayseri, Turkey
- 2. UCL, Dept Chem Engn, London WC1E 7JE, England
- 3. Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
Description
Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation of the parent framework from a sodalite (SOD) network to a diamond (DIA) network.
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