Published January 1, 2017
| Version v1
Journal article
Open
Synthesis of an F-BODIPY [2]catenane using the chemistry of bis(dipyrrinato) metal complexes
Creators
- 1. Ataturk Univ, Dept Chem, Fac Sci, TR-25240 Erzurum, Turkey
- 2. Anadolu Univ, Dept Chem, TR-26470 Eskisehir, Turkey
Description
ML2 type complexes of an olefin terminated 5H-dipyrrin ligand can be subjected to twofold ring closing metathesis to give bis(dipyrrinato)copper(II) and bis(dipyrrinato) zinc(II) [2] catenates. Demetalation of the copper(II) [2] catenate with KCN/N2H4 center dot H2O gave the corresponding bis(dipyrrin) [2] catenand. The boron difluoride complex of this bis(dipyrrin) was obtained as the first fluorescent F-BODIPY [2] catenane.
Files
bib-e91c0c78-bd96-403c-8db2-aa93ca297e07.txt
Files
(232 Bytes)
| Name | Size | Download all |
|---|---|---|
|
md5:a0e1abf25dc05d9c7b6bda3abd7be272
|
232 Bytes | Preview Download |