Yayınlanmış 1 Ocak 2017
| Sürüm v1
Dergi makalesi
Açık
A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting
Oluşturanlar
- 1. Istanbul Kemerburgaz Univ, Fac Pharm, Istanbul, Turkey
- 2. Swiss Fed Inst Technol, Lab Inorgan Chem, HCI H103 Vladimir Prelog Weg 1, CH-8093 Zurich, Switzerland
- 3. Gebze Tech Univ, Dept Chem, Kocaeli, Turkey
- 4. Yildiz Tech Univ, Dept Chem, Istanbul, Turkey
- 5. Istanbul Medeniyet Univ, Dept Engn Phys, Istanbul, Turkey
- 6. Syracuse Univ, Ctr Sci & Technol, 1-014, Syracuse, NY 13244 USA
- 7. Univ Bremen, Inst Inorgan Chem & Crystallog, Bremen, Germany
- 8. Berlin Inst Technol, Dept Food Chem & Toxicol, Gustav Meyer Allee 25, D-13355 Berlin, Germany
Açıklama
The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2 ''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework [{Cu(terpy)}(4)Cu(VO2)(4)(MTPPA-H)(2)]center dot 4H(2)O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA center dot MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.
Dosyalar
bib-2ec552c5-e478-4c0f-802d-4f25625f8f8e.txt
Dosyalar
(321 Bytes)
| Ad | Boyut | Hepisini indir |
|---|---|---|
|
md5:a3dbe774d6414df283c2a35183e38050
|
321 Bytes | Ön İzleme İndir |