Published January 1, 2009
| Version v1
Journal article
Open
New (kappa(2)-C,N)-palladacyclic complexes with benzimidazol-2-ylidene ligand: Synthesis, crystal structures and characterization
- 1. Adnan Menderes Univ, Dept Chem, TR-09010 Aydin, Turkey
- 2. Ondokuz Mayis Univ, Dept Phys, TR-55139 Kurupelit, Turkey
- 3. Ege Univ, Dept Chem, TR-35100 Bornova, Turkey
Description
Reaction of unsymmetrical benzimidazolium bromides (1) with Ag2O and subsequent transmetallation with chloro-bridged dinuclear palladacycle, [Pd(dmba)(mu-Cl](2) (dmba: N,N-dimethylbenzylamine) afforded benzannulated monocarbene complexes [Pd(dmba)(NHC)Cl], 2. The palladacycles (2a-c) were characterized by elemental analysis; NMR spectroscopy and the molecular structure of 2a and 2c were determined by X-ray crystallography. (C) 2009 Elsevier B.V. All rights reserved.
Files
bib-741c0733-4892-4a47-a89e-b9a64c230ffe.txt
Files
(257 Bytes)
| Name | Size | Download all |
|---|---|---|
|
md5:7aaa0a3fe232cd481ff12ed1ad317cc7
|
257 Bytes | Preview Download |