Published January 1, 2009 | Version v1
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3,3-Ethylenedithio-3,3a,4,5,10,10b-hexahydro-2H-furo[2,3-a]carbazole

  • 1. Mersin Univ, Fac Tech Educ, Dept Chem, TR-33500 Mersin, Turkey
  • 2. Hacettepe Univ, Dept Phys, TR-06800 Ankara, Turkey
  • 3. Hacettepe Univ, Fac Educ, Dept Chem Educ, TR-06800 Ankara, Turkey

Description

The title compound, C16H17NOS2, consists of a carbazole skeleton with tetrahydrofuran and dithiolane rings. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.57 (15)degrees. The cyclohexenone and tetrahydrofuran rings have envelope conformations, while the dithiolane ring adopts a twist conformation. In the crystal structure, pairs of weak intermolecular N-H center dot center dot center dot S hydrogen bonds link the molecules into centrosymmetric dimers with R-2(2)(16) ring motifs. Weak C-H center dot center dot center dot pi interactions may further stabilize the structure.

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