Published January 1, 2008
| Version v1
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Host/guest complex of beta-cyclodextrin/5-thia pentacene-14-one for photoinitiated polymerization of acrylamide in water
Creators
- 1. Yildiz Tech Univ, Dept Chem, TR-34210 Istanbul, Turkey
Description
beta-Cyclodextrin (beta-CD) was used to complex the photoinitiator, 5-thia pentacene-14-one (TX-A), yielding a water-soluble host/guest complex. IR, UV-Vis and fluorescence spectroscopy were employed to characterize complexed beta-CD/TX-A. Photoinitiated polymerization of acrylamide in water was achieved with beta-CD/TX-A in the presence of N-methyldiethanolamine (MDEA). Excellent polymerization yields were observed in air saturated solutions when MDEA was added. (C) 2008 Elsevier B.V. All rights reserved.
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