Published January 1, 2009
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The influence of moisture on deprotonation mode of imidazolinium chlorides with palladacycle acetate dimer
Creators
- 1. Adnan Menderes Univ, Dept Chem, TR-09010 Aydin, Turkey
- 2. Ondokuz Mayis Univ, Dept Phys, TR-55139 Kurupelit, Turkey
- 3. Ege Univ, Dept Chem, TR-35100 Bornova, Turkey
Description
Deprotonation of 1,3-diorganyl imidazolinium salts, 1, with N,C-type palladacyclic acetate dimer 2 afforded novel NHC coordinated complexes 3 along with ring opening hydrolysis products 4, which may coordinate to palladium center via NH group to give 5a. The hydrolysis necessitates the study of NHC complex formation in anhydrous media. The new compounds were characterized by spectroscopic methods and three of them (3c, 4c, 5a) by X-ray single-crystal diffraction studies. (C) 2009 Elsevier B. V. All rights reserved.
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