Published January 1, 2009
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Reactions of alkylidenepyrrolidines with alpha-chlorooximes and alpha-chlorohydrazones
Creators
- 1. Abant Izzet Baysal Univ, Dept Chem, TR-14280 Bolu, Turkey
- 2. Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales
Description
The reactions of alkylidenepyrrolidines with alpha-chlorooximes give isoxazoles via an acylation reaction followed by ring isomerisation. In contrast, and in line with a previous report, the corresponding alpha-chlorohydrazones give the simple acylation products. although in one instance a cycloadduct was also obtained. (C) 2009 Elsevier Ltd. All rights reserved.
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