Published January 1, 2009 | Version v1
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Rhodium catalyzed reaction of internal alkynes with organoborons under CO atmosphere: a product tunable reaction

  • 1. Izmir Inst Technol, Fac Sci, Dept Chem, TR-35430 Izmir, Turkey

Description

Alkynes react with organoborons under a CO atmosphere in the presence of a rhodium(I) catalyst to afford mainly 5-aryl-2(5H)-furanones, alpha,beta-unsaturated ketones, and indanones. The product selectivity can be tuned by modifying the reaction conditions. (C) 2009 Elsevier Ltd. All rights reserved.

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