Published January 1, 2018 | Version v1
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Palladium-catalysed reactions of conjugated enyne oxiranes with organoborons: A diastereoselective method of the synthesis of 2,4,5-trienol derivatives

  • 1. Izmir Inst Technol, Fac Sci, Dept Chem, TR-35430 Izmir, Turkey
  • 2. Ege Univ, Fac Sci, Dept Chem, TR-35040 Izmir, Turkey

Description

A palladium-catalysed reaction of conjugated enyne oxiranes with organoboron reagents is described. This method allows aryl-substituted vinylallenes containing a hydroxyl group on the allylic position to be synthesized, with good diastereomeric ratios, under mild conditions. (C) 2018 Elsevier Ltd. All rights reserved.

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