Yayınlanmış 1 Ocak 2010
| Sürüm v1
Dergi makalesi
Açık
New Synthetic Methodology for Construction of the 1,3,4,5-Tetrahydro-2H-1,3-benzodiazepin-2-one Skeleton
Oluşturanlar
- 1. Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey
- 2. Ataturk Univ, Dept Chem, TR-25240 Erzurum, Turkey
Açıklama
We hereby report a new synthetic methodology for construction of the 1,3,4,5-tetrahydro-2H-1,3-benzodiazepin-2-one skeleton. 2-(2-Carboxyethyl)benzoic acid was converted into the corresponding bis(acyl azide). Curtius rearrangement of the diazide followed by reaction with alcohols provided diurethane derivatives. Ring-closure reaction of the diurethanes with base resulted in formation of the 1,3-benzodiazepin-2-one skeleton.
Dosyalar
bib-451c1ff9-9088-44f1-a7df-f8175c422a43.txt
Dosyalar
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