Published January 1, 2010
| Version v1
Journal article
Open
New 1,2,4,5-tetrakis-(N-imidazoliniummethyl)benzene and 1,2,4,5-tetrakis(N-benzimidazoliummethyl)benzene salts as N-heterocyclic tetracarbene precursors: synthesis and involvement in ruthenium-catalyzed allylation reactions
- 1. Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey
- 2. Ege Univ, Dept Chem, TR-35100 Izmir, Turkey
- 3. Univ Rennes, CNRS, UMR 6226, F-35042 Rennes, France
Description
New tetraimidazolinium and tetrabenzimidazolium salts have been prepared Upon reaction with (BuOK)-Bu-t. they generate carbene ligands, which were associated in situ to [RuCp'(MeCN)(3)]PF6 to produce new ruthenium catalysts that are active for the Substitution of allylic substrates by amines, phenols, and carbonucleophiles The influence of the N-heterocyclic core as well as that of the N-substitutents at the periphery of the salts, on reactivity and regioselectivity have been exammed (C) 2009 Elsevier Ltd All rights reserved
Files
bib-2bfa2e04-43cd-43c4-ab1d-43c788a474fe.txt
Files
(327 Bytes)
| Name | Size | Download all |
|---|---|---|
|
md5:810163615b615aa62455decb7c7bd4fb
|
327 Bytes | Preview Download |