Development of ductile green flame retardant poly(lactic acid) composites using hydromagnesite&huntite and bio-based plasticizer

Turning brittle poly(lactic acid) (PLA) to ductile form via plasticizer inclusion is an effective option in the case of processing with high amounts of additives. Additionally, the integration of natural flame retardants to PLA involving bio-based plasticizer enables to use of environmentally friendly composites in conditions where fire resistance performance is required. In the current study, ductile green fire retardant PLA composites were manufactured using hydromagnesite & huntite (HH) as a natural fire retardant additive and acetyl tributyl citrate as a bio-based plasticizer. The influences of plasticizer and HH contents on the fire retardant, thermal and mechanical performances of the composites were explored. According to test results, the limiting oxygen index (LOI) value of PLA reduced from 29.2 to 28.0 and the UL-94 V rating changed from V2 to BC with the addition of 20 wt% plasticizer owing to the reduction in melt viscosity. The peak heat release rate (pHRR) and average heat release rate (avHRR) values increased steadily as the concentration of plasticizer increased due to the formation of a more porous residue structure stemming from the increased transportation rate of gases. In order to produce ductile flame retardant material, the plasticizer content was required to 20 wt% of HH. The highest LOI value (36.2) and UL-94 rating of V0 were achieved with the inclusion of 70 wt% HH in the presence of 20 wt% plasticizer. Improvement in impact resistance and reduction in tensile strength were observed as the added amount of plasticizer increased.