Published January 1, 2024
| Version v1
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Tailoring fluorescent ZIF-8 nanostructures through calix[4]pyrrole modification: tunable size and enhanced organic micropollutant removal capacity
- 1. Istanbul Tech Univ, Dept Polymer Sci & Technol, TR-34469 Maslak, Istanbul, Turkiye
- 2. Istanbul Tech Univ, Dept Chem, TR-34469 Maslak, Turkiye
- 3. Istanbul Tech Univ Nanotechnol Res, Applicat Ctr ITUNano, Istanbul, Turkiye
Description
Whitish-blue light emitting fluorescent ZIF-8 structures were synthesized by means of bis-carboxylate functional calix[4]pyrrole (BCCP) modification. The calix[4]pyrrole concentration was also manipulated to tune the sizes of the ZIF-8 structures. Moreover, the BCCP-modified ZIF-8 samples exhibited enhanced organic micropollutant removal capacity from aqueous solutions.
A size-controllable fluorescent ZIF-8 structure is synthesized through modification with a versatile supramolecule, bis-carboxylate functional calix[4]pyrrole. Upon modification, the micropollutant removal properties of ZIF-8 were adjustable.
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