Published January 1, 2023 | Version v1
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A DDQ-mediated ring-opening and aromatization cascade of a tetrahydrocarbazole-fused tetrahydrofuran for the synthesis of olivacine

  • 1. TUBITAK Marmara Res Ctr, TR-41470 Kocaeli, Turkiye
  • 2. Suleyman Demirel Univ, Dept Chem, TR-32260 Isparta, Turkiye

Description

It is introduced that an N-MOM-tetrahydrocarbazole-fused synthesis of olivacine. Upon treatment with DDQ ring-opening, MOM-removal and aromatization in one already known precursor for olivacine. Besides, several of N-MOM-protected tetrahydrocarbazole-1-one with tetrahydrofuran with Red-Al, have been made good

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