Yayınlanmış 1 Ocak 2010
| Sürüm v1
Dergi makalesi
Açık
Facile synthesis of 6-iodo-2,2 '-dipivaloyloxy-1,1 '-binaphthyl, a key intermediate of high reactivity for selective palladium-catalyzed monofunctionalization of the 1,1 '-binaphthalene core
Oluşturanlar
- 1. Univ Pannonia, Inst Chem, Dept Organ Chem, H-8201 Veszprem, Hungary
- 2. ThalesNano Inc, H-1031 Budapest, Hungary
Açıklama
A high-yielding procedure for selective monoiodination of 2,2'-dihydroxy-1,1'-binaphthyl (BINOL) is reported. 6-Iodo-2,2'-dipivaloyloxy-1,1'-binaphthyl, obtained in three steps starting from BINOL in 88% overall yield, proved to be a highly efficient substrate in various palladium-catalyzed coupling (Stille, Heck, Sonogashira, and Suzuki coupling) and carbonylation reactions compared to the analogous 6-bromo derivative. (C) 2010 Elsevier Ltd. All rights reserved.
Dosyalar
bib-5294abb0-e59f-48c9-aa75-284f26f25c53.txt
Dosyalar
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