Dropwise condensation reduces selectivity of sky-facing radiative cooling surfaces

Dew formation occurs frequently on radiative cooling surfaces used for cooling of buildings and for har-vesting atmospheric water as a result of dropwise condensation. The presence of these droplets can in turn alter the infrared emittance and performance of radiative cooling surfaces, in particular, selective emitters. This study experimentally investigates the impact of dropwise condensation on both the emit-tance and spectral selectivity of radiative cooling surfaces. Here, selective emitters supporting a large number of polydisperse acrylic droplets, as water droplet simulant, with contact angle ranging between 39 degrees and 62 degrees and surface area coverage between 20% and 52% were prepared and characterized. Spec-tral characterization revealed that the spectral emittance of the radiative cooling surfaces increased and broadened significantly in the presence of droplets. This was attributed to the absorption by the droplets. The emittance inside the long-wavelength infrared (LWIR) atmospheric transparency window increased slightly while the emittance outside increased significantly with increasing droplet surface area coverage and contact angle. This loss in spectral selectivity resulted in heat gain from radiation exchanges out-side the LWIR, such that a given radiative cooling surface attained a higher temperature when covered with droplets. Dew formation may thus present important limitations on the performance achievable by selective emitters in radiative cooling applications.(c) 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ )